Ball-Milled COF Electrolyte Boosts Solid-State Proton Battery Performance
Researchers report a mechanochemical (ball-milling) synthesis of a phosphoric acid-loaded covalent organic framework (PA@TP-COF) as a solid-state protonic electrolyte, avoiding the harsh solvents and long reaction times of conventional solvothermal COF synthesis. The ordered nanochannels of TP-COF combined with acid-base interactions with H3PO4 create continuous hydrogen-bonding networks that yield a high proton conductivity of 6.24×10⁻² S·cm⁻¹, low activation energy (0.14 eV), and a wide 5.6 V electrochemical stability window; assembled solid-state proton batteries retained 72.2% capacity after 1500 cycles at 1.0 A·g⁻¹. Twitter discussion of the paper consists mainly of straightforward reposts of the title and abstract highlights, with no substantive critical commentary or skepticism raised so far.
Discussion: 2 tweets from 2 authors · @elvahupin, @yxxwqhts_coys